Oill spills and Tar balls – know thine enemy

One of the more intriguing aspects of oil spills, including the DeepWater Horizon spill currently unfolding in the Gulf of Mexico (DeepSeaNews has covered it well), is the formation of tar balls.  These are globby blobs of bitumen-like material that are found on the sea floor or washed up on beaches after a spill. There's a few theories about how they form, but the general concept is that as the more volatile parts of the oil mixture evapourate, the mixture becomes thicker, heavier and stickier, until eventually the blob becomes heavier than seawater and sinks. On the bottom, the sticky blob incorporates sediment and its ball-like shape is reinforced by the rolling actions of currents or surf, in much the same way as you roll cookie dough into balls before putting them on the baking tray (mmmmmm….cookies….ahem). Sometimes this process makes for a grainy crust on the outside and a soft center, a bit like a Ferrero Rocher (mmmmm....chocolate....why do my analogies always involve food?).  There’s some other theories of formation that concern flocculation (oil sticking to clay) and emulsion (oil and water making a mousse of sorts - again with the food), but the prevailing idea seems to be that of smaller blobs of weathered oil coalescing and incorporating sediment. The net results is a gooey mess that is characteristically hard to remove if it sticks to you (or an animal), pongs of petroleum and is generally unpleasant.  The photo at left from NOAA's image library shows a tarball on a beach in California

Other than their B-grade horror movie nature (The Blob – aiieeeeee!) and the formation process above, I confess not knowing much about tar balls, so I went to the literature to see what’s out there. The answer: not much. A Web of Science search for “(tar ball) or tarball” 1945-2010 gets you precisely 26 hits. Now that is interesting! I would have thought that there would be far more, given the attention that is focused on oil spills when they happen. Much of the research has focused on chemical fingerprinting to identify where a given tar ball originated. In other words, the presence and absence of certain chemicals in a tar ball can tell you what sort of oil the ball formed from, and pretty accurately too. This has allowed some other studies that have shown that you have to be careful about blaming all the tar balls on a beach on one spill; there’s often a pretty good background level of tar balls from previous spills and even natural sources of oily substances. This is especially so for really small tar balls in the mm size range.

So what’s the long-term prognosis on tar balls in the environment? It doesn’t look like that question has been thoroughly answered yet.  Clearly they persist long after many more obvious signs of oil are gone.  Its tempting to think that they may be largely inert, especially those that form a good crust on the outside that reduces stickiness and prevents chemical interactions with the outside. But really, it seems like there’s a lot more work that needs to be done to understand these curious byproducts of oil spill accidents.